4-{[(5-Methyl-2-furyl)methylene]hydrazinocarbonyl}pyridinium chloride monohydrate

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4-{[(5-Methyl-2-fur­yl)methyl­ene]hydrazinocarbon­yl}pyridinium chloride monohydrate

The title compound, C(12)H(12)N(3)O(2) (+)·Cl(-)·H(2)O, was prepared by the reaction of N'-[(5-methyl-2-fur-yl)methyl-ene]isonicotino-hydrazide and hydro-chloric acid at room temperature. The entire molecule is approximately planar with a maximum deviation of 0.047 (2) Å. An intramolecular C-H⋯O interaction is observed. O-H⋯Cl, N-H⋯Cl, N-H⋯O, N-H⋯N, C-H⋯Cl and C-H⋯O hydrogen-bonds stabilize the...

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In the crystal structure of the title compound, C(7)H(11)N(2)O(2)S(+)·Cl(-)·H(2)O, the cations, anions and water mol-ecules are linked by inter-molecular N-H⋯O, N-H⋯Cl, O-H⋯O and O-H⋯Cl hydrogen bonds, forming layers stacked along [20].

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The title hydrate, C13H14N2O4·H2O, crystallizes with two formula units in the asymmetric unit (Z' = 2). The dihedral angles between the planes of the tetra-hydro-pyrimidine ring and the 4-hy-droxy-phenyl ring and ester group are 86.78 (4) and 6.81 (6)°, respectively, for one mol-ecule and 89.35 (4) and 3.02 (4)° for the other. In the crystal, the organic mol-ecules form a dimer, linked by a pai...

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In the title compound, C(15)H(18)N(2)O(5)·H(2)O, the pyrimidine ring adopts a flattened-boat conformation. The eth-oxy group attached to the benzene ring is in an extended conformation. The oxopyrimidine mol-ecules are linked into centrosymmetric R(2) (2)(20) dimers by O-H⋯O hydrogen bonds. The dimers are linked by N-H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane...

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4-[(2-Chloro­ethyl)amino]quinolinium chloride monohydrate

In the title salt hydrate, C(11)H(12)ClN(2) (+)·Cl(-)·H(2)O, the quinolin-ium core is essentially planar (r.m.s. deviation = 0.027 Å) with the chloro-ethyl side chain being almost orthogonal to the core [C-N-C-C torsion angle = -80.0 (3)°]. In the crystal packing, the water mol-ecule bridges three species, forming donor inter-actions to two chloride anions and accepting a hydrogen bond from the...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809028426